書誌事項
- タイトル別名
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- A differential pulse polarographic method for the determination of trace amounts of osmium(VIII) using a polarographic maximum wave.
- ビブン パルス ポーラログラフホウ ニ オケル キョクダイハ オ モチイル ビ
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A differential pulse polarographic method for the determination of trace osmium (VIII) is described. In the presence of about 2000-times Cys, osmium (VIII) in a 1.0 mol/dm3 hydrochloric acid solution exhibits a well-defined maximum wave, or peak at -0.85 V vs. SCE. The peak height in the presence of Cys was amplified about 1600-times. The peak height depends on the concentration of hydrochloric acid, and reaches its maximum in a concentration range of 0.75 to 1.25 mol/dm3. Concerning the existence of Cys, the maximum wave, or peak, was complicatedly controlled by the adsorption, catalytic, and/or kinetic currents. Although Ag+, Cd2+, Cu2+, Hg2+, Pb2+and Zn2+, which were highly affinitive with Cys, did not interfere with the osmium peak, an excess amount of Cu2+ did interfere. Osmium (VIII) was directly detected by this method over a concentration range of 8.0 × 10-10 to 2.7 × 10-7 mol/dm3 ; the detection limit was 3.5 × 10--10mol/dm3 (k =3).
収録刊行物
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- 分析化学
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分析化学 46 (3), 169-174, 1997
公益社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679029940736
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- NII論文ID
- 110002907191
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- NII書誌ID
- AN00222633
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- COI
- 1:CAS:528:DyaK2sXhvVKntrg%3D
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- NDL書誌ID
- 4160652
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- ISSN
- 05251931
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- NDL-Digital
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可