Polynuclear Structures Derived from Dinuclear Metal Complex with Phenol Based Macrocyclic Ligand
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- MIYAZATO Yuji
- Waseda University, Faculty of Science and Engineering
Bibliographic Information
- Other Title
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- 二核化大環状配位子錯体によって創られる多様な分子構造
- 2カクカ ダイカンジョウ ハイイシ サクタイ ニ ヨッテ ツクラレル タヨウ ナ ブンシ コウゾウ
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Abstract
Dinuclear metal complex with phenol based dinucleating macrocyclic ligand (L2-) derived from the [2+2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane can act as ‘complex as metal’, since axial position of the dinuclear complex is available for accepting donation from ‘another ligand’. A tetranuclear Fe(III) complex, [{Fe2(L)(CH3COO)}2(μ-O)2](PF6)2, was obtained by linking two {Fe2(L)(OAc)} units with two oxo anions. In addition, a dinuclear copper (II) complex, [Cu2(L)](ClO4)2, was reacted with [Cr(ox)3]3- and [Co(CN)6]3- as ‘complex as bridging ligand’, to afford [Cu2(L)]3[Cr(ox)3]2·6MeOH having a discrete octanuclear structure and [Cu2(L)]3[Co(CN)6]2·6MeOH·2DMF having 2-D grid structure, respectively.
Journal
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- Nihon Kessho Gakkaishi
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Nihon Kessho Gakkaishi 52 (5), 246-249, 2010
The Crystallographic Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679063085824
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- NII Article ID
- 10027673065
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- NII Book ID
- AN00188364
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- COI
- 1:CAS:528:DC%2BC3MXjtFSqsA%3D%3D
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- ISSN
- 18845576
- 03694585
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- NDL BIB ID
- 10882216
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed