立体選択性および反応経路と分子構造

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タイトル別名
  • Molecular Structures and Chemical Reaction Paths
  • リッタイ センタクセイ オヨビ ハンノウ ケイロ ト ブンシ コウゾウ

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説明

Based on the molecular structures of the reaction products determined by X-ray analysis, correlations between molecular structures and reaction mechanism are reported in this article. High selectivity for electrophilic addition of Br2 or BrOH and Michael addition of dimethyl malonate to the chiral sulf inyl compounds are explained in terms of the established configurations and conformations of the products. A study on a series of the compounds produced by Bipolar additions to thiadizoles and thiadizoline reveals that a bond switch takes place at the π-hypervalent sulfur atom during these reactions. In the last section recent topics on a relationship between reaction paths and molecular structures proposed by Burgi are reviewed.

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