Stoructural science and various functions in hydorogen-bond materials. Protonic Polaron. A New Model of Dynamical Behavior of Protons forming Hydrogen Bonds.

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  • 水素結合における構造物性と機能　　水素結合の新しい見方　　ｐｒｏｔｏｎｉｃ　ｐｏｌａｒｏｎ
  • スイソ ケツゴウ ノ アタラシイ ミカタ protonic polaron

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Abstract

Recent investigations on the dynamics of the proton forming hydrogen bond in solids are reported. It is emphasized that simple tunneling picture of proton within a static double minimum potential does not properly describe the properties of hydrogen bond. Instead, protonic polaron state is proposed to describe the ground state of the system. Experimental results of neutron spectroscopy are shown to be censistent with this new picture.

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