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- 大橋 裕二
- 東京工業大学理学部天然物化学研究施設
書誌事項
- タイトル別名
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- Structural Study of Asymmetric Hydrogenation
- フセイ セッショク スイソカ ハンノウ ノ コウゾウ カガク
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抄録
Asymmetric hydrogenation catalyzed by transition metal complexes has been comprehensively studied. To reveal the mechanism of inducing the asymmetry, the complexes of his (dimethylglyoximato) cobalt and asymmetric amine are the most interesting because the intermediate complexes are easily isolated and crystallized. On the basis of the structure analyses of such complexes, we proposed that the asymmetry of the amine is transferred to the products at a transition state through the distortion of the his (dimethylglyoximato) cobalt moiety. This hypothesis was supported by the calculation of the potential energy at the transition state of which the structure was derived from the analysed ones.
収録刊行物
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- 日本結晶学会誌
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日本結晶学会誌 19 (6), 303-323, 1977
日本結晶学会
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詳細情報 詳細情報について
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- CRID
- 1390282679064599936
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- NII論文ID
- 130000790939
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- NII書誌ID
- AN00188364
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- COI
- 1:CAS:528:DyaE1MXkt1Oqsb8%3D
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- ISSN
- 18845576
- 03694585
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- NDL書誌ID
- 1916053
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可