Novel Photopolymerization Initiation System Highly Sensitive to the Visible Laser: α-Amino Ketones, Additives to Enhance Sensitivity

  • KUNITA Kazuto
    Synthetic Organic Chemistry Laboratories, R&D Management Headquarters, FUJIFILM Corporation
  • SORORI Tadahiro
    Highly Functional Materials Research Laboratories, R&D Management Headquarters, FUJIFILM Corporation

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Other Title
  • 可視レーザー対応高感度光重合開始系 ─α-アミノケトン増感助剤─
  • 可視レーザー対応高感度光重合開始系 : α-アミノケトン増感助剤
  • カシ レーザー タイオウ コウカンド ヒカリ ジュウゴウ カイシケイ : a-アミノケトン ゾウカン ジョザイ

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Description

A highly sensitive photopolymerization initiation system, corresponding to the visible laser with the wavelength of 488nm, was investigated. We already reported an electron-transfer initiation system consisting of a merocyanine dye and a triazine initiator. The sensitivity of this system was too low to commercially apply it to CTP. We have found that a-amino ketones have an excellent ability to improve its sensitivity by using them as additives to our initiation system. These ketones have been found to improve the sensitivity more than twice and to show excellent thermal stability, which satisfy the requirements to realize commercialization of CTP.

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