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- 大津 博義
- 浦項工科大学先端材料科学部
書誌事項
- タイトル別名
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- Isolation of Labile S<sub>3</sub> Molecule in Porous Coordination Network and its Structure Determination by <i>Ab Initio</i> Powder X-ray Analysis
- 細孔性ネットワーク錯体を用いたS₃分子の単離と粉末X線回折による構造決定
- サイコウセイ ネットワーク サクタイ オ モチイタ S ₃ ブンシ ノ タンリ ト フンマツ Xセン カイセツ ニ ヨル コウゾウ ケッテイ
- Isolation of Labile S3 Molecule in Porous Coordination Network and its Structure Determination by Ab Initio Powder X-ray Analysis
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抄録
In this review, we report isolation of unstable tri-sulfur, S3, in a porous coordination network which is used as a crystalline molecular flask. The ozone-like structure of S3 in a pore was determined by ab initio X-ray powder diffraction analysis. The S3 in the pore was interacted with iodine which faces to the pore of the network. The S3 in the network was quite stable unlike unstable gaseous S3 molecule because of the S-I interaction in the pore. Furthermore, the S3 in the network could be transformed to S6 by mechanical grinding or heating in the presence of NH4Cl. We will introduce new chemistry of small sulfur based on crystal structure.
収録刊行物
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- 日本結晶学会誌
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日本結晶学会誌 56 (5), 323-328, 2014
日本結晶学会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282679065713792
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- NII論文ID
- 130004714203
- 40020256053
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- NII書誌ID
- AN00188364
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- ISSN
- 18845576
- 03694585
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- NDL書誌ID
- 025895407
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可