Effects of Chemical Structure and Temperature on Sphere-to-Rod Transition of Micelles in the Aqueous Solution of [Sodium Salicylate]/[Quaternay Ammonium Salt-Type Cationic Surfactant], as Determined by Spin-Probe ESR
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- HORIUCHI Teruo
- Material Science Research Center, Lion Corporation
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- YOSHII Toru
- Material Science Research Center, Lion Corporation
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- TAJIMA Kazuo
- HRC, Department of Chemistry, Faculty of Engineering, Kanagawa University
書誌事項
- タイトル別名
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- Effects of Chemical Structure and Temperature on Sphere-to-Rod Transition of Micelles in the Aqueous Solution of [Sodium Salicylate]/[Quaternary Ammonium Salt-Type Cationic Surfactant]
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By spin probe ESR, examination was made of the effects of temperature on aggregate properties of quaternary ammonium salt cationic surfactant solution with sodium salicylate (NaSal) as a function of 1) alkyl chain length and 2) number of 2-hydroxyethyl groups. For detailed study of rod-like micelle fluidity, measurement was made of the ESR spectra of 5NS, 12NS and 16NS incorporated in micelles in aqueous solution of [NaSal]/[HMODA]. The order parameter (S33) for 5NS considerably exceeded that of 16NS. Fluidity about the spin probe 5NS was much less. The hydrophilic layer of rod-like micelles in aqueous solution of [NaSal]/[HMODA] was more rigid compared to the hydrophobic core. The order parameter of 5NS decreased remarkably at 45-55°C but showed no significant change for 12NS and 16NS spin probes. The hyperfine splitting constant of 5NS (aN′), which reflects polarity about a spin probe, decreased remarkably at 45-55°C. Dehydration of 2-hydroxyethyl groups in [HMODA] took place with increase in temperature, with resultant reduction in the hydrophilicity of [HMODA]. For rod-like aggregates in aqueous solution of [NaSal]/[HMODA], a clear transition temperature was noted, which increased with alkyl chain length and the number of 2-hydroxyethyl groups in cationic surfactants.<br>
収録刊行物
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- Journal of Oleo Science
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Journal of Oleo Science 52 (8), 421-428, 2003
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679067632640
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- NII論文ID
- 130000060487
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- NII書誌ID
- AA11503337
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- COI
- 1:CAS:528:DC%2BD3sXlvFSgsrc%3D
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- ISSN
- 13473352
- 13458957
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- NDL書誌ID
- 6606894
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可