Enzymatic Synthesis of Phenyl Fatty Hydroxamic Acids from Canola and Palm Oils

DOI Web Site Web Site 被引用文献1件 参考文献20件
  • Jahangirian Hossein
    Department of Chemistry, Faculty of Science, Universiti Putra Malaysia
  • Haron Md Jelas
    Department of Chemistry, Faculty of Science, Universiti Putra Malaysia
  • Silong Sidik
    Department of Chemistry, Faculty of Science, Universiti Putra Malaysia
  • Yusof Nor Azah
    Department of Chemistry, Faculty of Science, Universiti Putra Malaysia

この論文をさがす

抄録

Phenyl fatty hydroxamic acids (PFHAs) were synthesized from canola or palm oils and phenyl hydroxylamine (FHA) catalyzed by Lipozyme TL IM or RM IM. The reaction was carried out by shaking the reaction mixture at 120 rpm. The optimization was carried out by changing the reaction parameters, namely; temperature, organic solvent, amount and kind of enzyme, period of reaction and the mol ratio of reactants. The highest conversion was obtained when the reaction was carried out under the following conditions: temperature, 39°C; solvent, petroleum ether; kind and amount of lipase, 80 mg Lipozyme TL IM/mmol oil; reaction period, 72 h and FHA-oil ratio, 7.3 mmol FHA/ mmol oil. The highest conversion percentage of phenyl hydroxylaminolysis of the Ladan and Kristal brands commercial canola oils, palm stearin and palm kernel oils were 55.6, 52.2, 51.4 and 49.7 %, respectively.

収録刊行物

被引用文献 (1)*注記

もっと見る

参考文献 (20)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ