Aldol Condensation of Several Monoterpene Aldehydes with Acetone by Synthetic Zeolite Catalysts

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  • 合成ゼオライト触媒によるモノテルペンアルデヒド類とアセトンとのアルドール縮合
  • ゴウセイ ゼオライト ショクバイ ニヨル モノテルペンアルデヒドルイ ト アセ

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Abstract

Examination was made of aldol condensations of (+) -citronellal (1), trans-citral (2), cis-citral (3), (+) -perillaldehyde (4), α-campholenic aldehyde (5) and (+) -myrtenal (6) with acetone by synthetic zeolite catalysts and the following results were obtained. With 2020 AH, HSZ-320CAA or HSZ-820NAA zeolites, (7) (12) were obtained from (1) (6) as the principal products, respectively and evaluated for odor; the odor emitted by 8 indicated potential application as flavor constituents.

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