塩化クロム(III)六水塩の種々の有機溶媒中からのクロムの電析

書誌事項

タイトル別名
  • Electrodeposition of Chromium from Chromium (III)
  • (III) 六水塩の種々の有機溶媒中からのクロムの電析

説明

The present study has been made to investigate the electrodeposition of chromium from CrCl3⋅6H2O-HCONH2, CrCl3⋅6H2O-HCON (CH3)2, and CrCl3⋅6H2O-(CH3)2SO solutions with additives. The solubility of CrCl3⋅6H2O in the organic solvents and the specific conductance of the solutions were measured, and these values were found to be generally lower than those in aqueous systems. The optimum conditions of the electrolysis in organic solvents were determined. Thin, bright and smooth deposits were obtained from the above conditions with a low cathode current efficiency (less than 30%). Chromium deposition mechanism is discussed in terms of the formation of chromium (III) complex ions in FA, DMF and DMSO solvents.

収録刊行物

  • 金属表面技術

    金属表面技術 34 (1), 12-18, 1983

    一般社団法人 表面技術協会

被引用文献 (1)*注記

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詳細情報 詳細情報について

  • CRID
    1390282679088464256
  • NII論文ID
    130003994531
  • DOI
    10.4139/sfj1950.34.12
  • ISSN
    18843395
    00260614
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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