８‐ヒドロキシキノリン水溶液において生成した鉄のアノード酸化被膜の構造と耐食性
-
- 金野 英隆
- 北海道大学工学部
-
- 永山 政一
- 北海道大学工学部
-
- Leidheiser Jr. Henry
- Center for Surface and Coating Res., Lehigh Univ.
-
- Granata Richard D.
- Center for Surface and Coating Res., Lehigh Univ.
書誌事項
- タイトル別名
-
- The Composition and Properties of a Protective Layer Formed on a Steel by Anodizing with 8-Hydroxyquinoline
この論文をさがす
説明
Carbon steel specimens were anodized by a two step procedure, first in a borate solution and second in a borate solution containing 8-hydroxyquinoline [HQ]. The resulting surface inhibits cathodic reactions such as oxygen reduction and hydrogen evolution, and it has good corrosion resistance in aerated chloride media of pH 3-10. The composition and structure of the formed layer were analyzed by UV-VIS-IR reflectance spectroscopy, Auger electron spectroscopy combined with argon ion sputtering, conversion electron Mössbauer spectroscopy, and ellipsometry. The results indicate that the protective layer is composed of two layers: the outer layer is less than 40nm in thickness and consists of condensation products of HQ and HQ derivatives formed by the anodic polarization, and the inner layer is less than 3nm in thickness and consists of Fe-HQ and/or-HQ derivatives complexes. Electrochemical measurements revealed that the inner Fe complex layer is responsible for the corrosion protection in aerated chloride media.
収録刊行物
-
- 金属表面技術
-
金属表面技術 35 (8), 402-408, 1984
一般社団法人 表面技術協会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390282679088921088
-
- NII論文ID
- 130003809992
-
- ISSN
- 18843395
- 00260614
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可