Effect of Preservation in the Air on the Hydriding Characteristics of the LaNi4.7Al0.3 Alloy Treated by Anhydrous Hydrogen Fluoride.

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  • 無水フッ化水素で表面改質したLaNi4.7Al0.3の水素吸蔵特性におよぼす大気保存の影響
  • ムスイ フッカ スイソ デ ヒョウメン カイシツシタ LaNi4.7Al0.3

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Abstract

Hydriding characteristics of LaNi4.7Al0.3 alloys with surfaces modified by high-purity anhydrous HF were evaluated after long-term preservation in air. Affected by poisoning species in air, untreated alloy hydriding activity was enormously decreased. HF-treated alloys with a modified surface layer containing metal fluoride NiF2, LaF3 and AlF3 maintained relatively high activity. In high-humidity air, metal fluoride NiF2 reacted with moisture to form hydrous Ni(OH)2, and permeation of poisonous species such as O2, CO and CO2 was markedly inhibited by moisture-condensed hydrate screens.

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