Estimation of Rotational and Translational State of Iron Pentacalbonyls under Supersonic Molecular Beam Condition by Using Infrared Diode Laser.
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- HONDA Kazuhiro
- Fac. of Eng., Kanagawa Inst. of Tech.
Bibliographic Information
- Other Title
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- 赤外半導体レーザーを用いた超音速分子線中の鉄カルボニル鎖体の回転・並進状態の評価
- セキガイ ハンドウタイ レーザー オ モチイタ チョウオンソク ブンシセンチュ
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Abstract
The rotational and translational states of Iron Pentacarbonyls (Fe(CO)5) were caluculated under supersonic molecular beam conditions. High-resolution infrared absorption spectra indicated that the rotational temperature of Fe(CO)5 in Ar buffer gas was 6K, that in Ne buffer gas was 9K, and He buffer gas was 14K. Time-resolved infrared absorption spectra indicated that velocity of Fe(CO)5 in Ar buffer gas was 1, 400ms-1, corresponding to Mach 4, and that in He buffer gas was 2, 700ms-1, corresponding to Mach 8.
Journal
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- Journal of The Surface Finishing Society of Japan
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Journal of The Surface Finishing Society of Japan 48 (11), 1131-1133, 1997
The Surface Finishing Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679092593920
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- NII Article ID
- 10002260356
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- NII Book ID
- AN1005202X
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- ISSN
- 18843409
- 09151869
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- NDL BIB ID
- 4334606
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed