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Studies Concerning the Factors Affecting the Formation of Cyclohexanone Intermediates in the Catalytic Hydrogenation of Phenols. I. Hydrogenation of p-Cresol over Various Pd-C Catalysts.
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- Higashijima Michio
- Department of Applied Chemistry, Tokyo University of Agriculture and Technology
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- Nishimura Shigeo
- Department of Applied Chemistry, Tokyo University of Agriculture and Technology
Bibliographic Information
- Other Title
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- Studies Concerning the Factors Affecting the Formation of Cyclohexanone Intermediates in the Catalytic Hydrogenation of Phenols. I. Hydrogenation of <i>p</i>-Cresol over Various Pd–C Catalysts
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Description
The catalytic hydrogenation of p-cresol with commercial Pd on active carbon (Pd–C), water-washed Pd–C (Pd–C–N), acid-treated Pd–C (Pd–C–A), and base-treated Pd–C (Pd–C–B) has been kinetically studied in cyclohexane as a solvent under 0.15–8.0 MPa hydrogen pressure at 80°C. Under each reaction condition, the hydrogenation rate constants for the cresol and the ketone intermediate, k1+k3 and k2, respectively, the relative reactivity of the ketone to the cresol (K) and the ratio of the adsorption coefficient of the ketone to that of the cresol (b2/b1) were determined on the basis of a Langmuir–Hinshelwood model. Regardless of the difference in the nature of the catalysts, hydrogenations with these catalysts always gave high selectivities of 0.85–1.0 for the formation of the ketone intermediate, and small values of 0.014–0.62 for the relative reactivity (K). The small values of K over Pd–C and Pd–C–B were shown to be mostly due to the small values of k2/(k1+k3). In contrast, even smaller values of K over Pd–C–N and Pd–C–A were found due to a great difference in the strength of adsorption between the cresol and the ketone intermediate. In general, both the values of K and k2/(k1+k3) increase with increasing hydrogen pressure. All of the experimental results show that both the alkaline impurities associated with catalyst preparation and the hydrogen pressure are the most important factors affecting the formation of the ketone intermediate.
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 65 (3), 824-830, 1992
The Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679094501760
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- NII Article ID
- 130004147624
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- ISSN
- 13480634
- 00092673
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed