Benzo[<i>b</i>]cyclohepta[e][1,4]thiazines and Their Diazine Analogues. III. π-Electronic Structures of 5<i>H</i>,11<i>H</i>+-Cyclohepta[<i>b</i>]quinoxalinium Ions and Their O- and S-Analogues
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- Kurihara Teruo
- Department of Chemistry, Faculty of Science, Josai University
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- Shindo Kimio
- Department of Chemistry, Faculty of Science, Josai University
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- Ishikawa Sumio
- Department of Chemistry, Faculty of Science, Josai University
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- Nozoe Tetsuo
- Tokyo Research Laboratories, Kao Corporation
書誌事項
- タイトル別名
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- Benzo(b)cyclohepta(e)(1,4)thiazines and Their Diazine Analogues. III. .PI.-Electronic Structures of 5H,11H+-Cyclohepta(b)quinoxalinium Ions and Their O- and S-Analogues.
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説明
π-Electronic structures of 5H,11H+-cyclohepta[b]quinoxalinium ions and their O- and S-analogues were elucidated by means of 1H and 13C NMR spectra, electronic spectra, and theoretical calculations. Consequently, it was shown that these compounds had very stable aromatic characters with positive resonance energies and that the 6π-tropylium-6π-benzonoid form plays an important role for the π-conjugation structure.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 64 (9), 2668-2676, 1991
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679095806848
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- NII論文ID
- 130001998696
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- ISSN
- 13480634
- 00092673
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
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