Solvatochromic Linear Solvation Energy Relationships for Solubility of O2 in Various Solvents.

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  • Che Yong
    Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Tokuda Koichi
    Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Ohsaka Takeo
    Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology

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  • Solvatochromic Linear Solvation Energy

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Linear solvation energy relationships for solution of O2 in 27 solvents have been examined. Multiple linear regression equations for mole fraction solubility of O2 are developed based on Hildebrand’s solubility parameter as well as the π*, α, and β solvatochromic parameters describing the solvent polarizability/dipolarity, hydrogen bond acidity and hydrogen bond basicity, respectively. Use of the combination of these parameters enables the medium effect on solution of O2 to be correlated and interpreted in a conceptually simple manner.

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