Efficient Dimerization of Formic Acid in Aqueous Solution Induced by Ar-Arc Plasma.

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Introduction of argon-arc plasma into an aqueous solution of formic acid resulted in the formation of oxalic acid. The reaction conditions for the dimerization were studied. The maximum yield of oxalic acid reached 47–50% when the reaction was carried out using sodium formate or calcium formate. Dimerization of acetic acid was also examined.

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