Photochemical nucleophilic substitution reactions of methyl substituted derivatives of p- and o-nitroanisole.

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  • Sawaura Masaki
    Department of Chemistry, Faculty of Science, Tohoku University
  • Mukai Toshio
    Department of Chemistry, Faculty of Science, Tohoku University

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  • Photochemical Nucleophilic Substitution Reactions of Methyl Substituted Derivatives of <i>p</i>- and <i>o</i>-Nitroanisole

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Photosubstitution reactions of several methyl substituted derivatives of p- and o-nitroanisole with hydroxide ion were investigated. The methyl substituent seemed to show an uncertain (probably electronic) effect in addition to the steric effect for the replacement of both the methoxy and the nitro groups. Mainly, the replacement reaction of the nitro group is discussed.

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