Interfacial Nanochemistry in Liquid-Liquid Extraction Systems

DOI PDF Web Site 被引用文献18件 参考文献174件
  • Watarai Hitoshi
    Department of Chemistry, Graduate School of Science, Osaka University
  • Tsukahara Satoshi
    Department of Chemistry, Graduate School of Science, Osaka University
  • Nagatani Hirohisa
    Department of Natural Science, Hyogo University of Teacher Education
  • Ohashi Akira
    Department of Environmental Sciences, Faculty of Science, Ibaraki University

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説明

Recent development of the interfacial nanochemistry in the solvent extraction systems is reviewed, as well as the development of measurement methods for interfacial reactions. The studies on specific reactions at the interface of various metal extraction systems have elucidated essential modes of the interfacial reactions, including the interfacial adsorption, the interfacial complexation, and the interfacial aggregation. The catalytic role of the liquid-liquid interface in the solvent extraction kinetics and the molecular recognition ability of the self-assembled metal complexes at the interface were emphasized. Spectroscopic studies on the rotational and translational dynamics of fluorescent molecules, a single molecule in some cases, at the interface are also discussed. The utility of the molecular dynamics simulations is demonstrated in the discussions of the solvent structure in the interfacial region and of the stability of surface active molecules at the interface.

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