The Crystal and Molecular Structure of μ-Oxo-bis[bromotriphenylantimony(V)], [SbBr(C6H5)3]2O
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- Ouchi Akira
- Department of Chemistry, College of Arts and Sciences, The University of Tokyo
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- Sato Shoichi
- The Institute for Solid State Physics, The University of Tokyo
書誌事項
- タイトル別名
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- The crystal and molecular structure of .MU.-oxo-bis-[bromotriphenylantimony(V)], [SbBr(C6H5)3]2O.
- 公開日
- 1988
- DOI
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- 10.1246/bcsj.61.1806
- 公開者
- 公益社団法人 日本化学会
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説明
The crystal and molecular structure of the title complex was determined by the single-crystal X-ray diffraction method. The crystallographic data are: monoclinic, space group P21⁄c, a=19.164(6), b=19.020(9), c=18.649(7) Å, β=95.06(3)°, and Z=8 (16 metal atoms are in a unit cell). There are two crystallographically independent dimeric [SbBr(C6H5)3]2O molecules, which are almost in the same form. Each antimony atom is bonded with three phenyl carbon atoms equatorially and one bromine as well as one bridging oxygen atoms axially, being in a trigonal-bipyramidal geometry. The Sb–O–Sb′ angles are 170.2(7) and 176.6(8)°, while the Sb–O lengths are in the range of 1.931(13)—1.958(13) Å, which are shorter than the sum of their covalent radii of the atoms: 2.15 Å.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 61 (5), 1806-1808, 1988
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679104117120
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- NII論文ID
- 130001981212
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- ISSN
- 13480634
- 00092673
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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