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- Terada Akira
- Department of Chemistry, Kyushu Institute of Technology
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- Tanoue Yasuhiro
- Department of Chemistry, Kyushu Institute of Technology
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- Hatada Akira
- Department of Chemistry, Kyushu Institute of Technology
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- Sakamoto Hiroshi
- Department of Chemistry, Kyushu Institute of Technology
書誌事項
- タイトル別名
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- Synthesis of shikalkin (.+-.shikonin) and related compounds.
抄録
The key intermediate, 2-formyl-1,4,5,8-tetramethoxynaphthalene, was prepared through 1,4,5,8-tetramethoxynaphthalene, which was obtained from 1,5-naphthalenediol via three steps or from naphthazarin via one step. A total synthesis of shikalkin and dihydroshikalkin have been accomplished with this aldehyde via a side-chain introductions with Grignard reactions and the following demethylations.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 60 (1), 205-213, 1987
公益社団法人 日本化学会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282679105515904
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- NII論文ID
- 130001982511
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- ISSN
- 13480634
- 00092673
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可