Facile synthesis of (2S,3R,4R)-2-hydroxymethyl-3,4-pyrrolidinediol and 4-acetamido-1,2,3-tri-O-acetyl-4-deoxy-L-xylopyranose from the photoproduct of D-mannose.

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  • Facile Synthesis of (2<i>S</i>,3<i>R</i>,4<i>R</i>)-2-Hydroxymethyl-3,4-pyrrolidinediol and 4-Acetamido-1,2,3-tri-<i>O</i>-acetyl-4-deoxy-<scp>l</scp>-xylopyranose from the Photoproduct of <scp>d</scp>-Mannose

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(Synthesis of 2S,3R,4R)-2-hydroxymethyl-3,4-pyrrolidinediol and 4-acetamido-1,2,3-tri-O-acetyl-4-deoxy-L-xylopyranose were attained in four steps from D-mannose, using iron(III)-catalyzed photoreaction as a key reaction.

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