On the Mechanism of the Vinyl Transetherification Reaction Catalyzed by Mercuric Acetate

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  • Yuki Heimei
    Department of Chemistry, Faculty of Engineering Science, Osaka University
  • Hatada Koichi
    Department of Chemistry, Faculty of Engineering Science, Osaka University
  • Nagata Kazuhiko
    Department of Chemistry, Faculty of Engineering Science, Osaka University

書誌事項

公開日
1970
DOI
  • 10.1246/bcsj.43.1817
公開者
公益社団法人 日本化学会

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説明

The vinyl interchange reaction of methyl vinyl ether and methanol, methanol-d4, or ethanol catalyzed by mercuric acetate has been studied. Some organomercuric compounds have been isolated from the reaction mixture, and their catalytic activity for the interchange reaction has been examined. From these results, the mechanism proposed by Watanabe and Conlon (J. Amer. Chem. Soc., 79, 2828 (1957)) has been confirmed and further details of the reaction mechanism are discussed.

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