Syntheses of Isoprenoids from Isoprene. III. The Dimerizations of Dimethylcyclopropanes

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  • Tanaka Juntaro
    Department of Synthetic Chemistry, Faculty of Engineering, Shizuoka University
  • Katagiri Takao
    Department of Synthetic Chemistry, Faculty of Engineering, Shizuoka University
  • Takabe Kunihiko
    Department of Synthetic Chemistry, Faculty of Engineering, Shizuoka University
  • Sakamoto Tadashi
    Department of Synthetic Chemistry, Faculty of Engineering, Shizuoka University

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1,1-Dimethylcyclopropane(I) was found to dimerize selectively by the action of boron trifluoride etherate. In the products, compound (III), which had been presumed, and the reaction intermediates (VII and VIII) were identified. The reaction mechanism was discussed. 1,2-Dimethylcyclopropane(VI) gave the same products.

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