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Synthesis and Halochromism of 4- and 6-Styryl-2-aminotropones
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- Imafuku Kimiaki
- Department of Chemistry, Faculty of Science, Kumamoto University
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- Matsumura Hisashi
- Department of Chemistry, Faculty of Science, Kumamoto University
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Description
The methylation of 4-styryltropolones with diazomethane afforded two isomers, 2-methoxy-4-styryltropones and 2-methoxy-6-styryltropones. Their reactions with ammonia gave the corresponding 2-amino-4-styryltropones and 2-amino-6-styryltropones, respectively, by normal nucleophilic substitution. Infrared and ultraviolet absorption spectra were measured. The halochromism of 2-aminotropones was also examined, the halochromic shifts being found to be linearly correlated with the Hammett substituent constants.
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 46 (1), 199-203, 1973
The Chemical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679112822400
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- NII Article ID
- 130001974844
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- ISSN
- 13480634
- 00092673
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed