Reaction of dimethyl sulfoxide-trifluoroacetic anhydride with anilines, phenols, and thiophenols.
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- Hiraki Yuji
- Department of Chemistry, Faculty of Science, Kyoto University
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- Kamiya Masahiro
- Department of Chemistry, Faculty of Science, Kyoto University
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- Tanikaga Rikuhei
- Department of Chemistry, Faculty of Science, Kyoto University
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- Ono Noboru
- Department of Chemistry, Faculty of Science, Kyoto University
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- Kaji Aritsune
- Department of Chemistry, Faculty of Science, Kyoto University
書誌事項
- 公開日
- 1977
- DOI
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- 10.1246/bcsj.50.447
- 10.1002/chin.197721141
- 公開者
- 公益社団法人 日本化学会
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説明
The reaction of dimethyl sulfoxide–trifluoroacetic anhydride complex with anilines, phenols, and thiophenols was studied, and the following results were obtained. (1) The yields of a methylthiomethylated product were improved with anilines. The reaction proceeded without significant amount of tar, the unreacted anilines being easily recovered. (2) Selective ortho-methylthiomethylation took place with phenols in good yields at lower temperature, para-methylthiomethylation occurring at higher temperature. (3) Methylthiomethylation took place with thiophenols on a sulfur atom of thiophenol at room temperature in a simple process.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 50 (2), 447-452, 1977
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679113907712
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- NII論文ID
- 130001970843
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- ISSN
- 13480634
- 00092673
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可