ChemInform Abstract: REACTION OF DIMETHYL SULFOXIDE‐TRIFLUOROACETIC ANHYDRIDE WITH ANILINES, PHENOLS, AND THIOPHENOLS
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- Hiraki Yuji
- Department of Chemistry, Faculty of Science, Kyoto University
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- Kamiya Masahiro
- Department of Chemistry, Faculty of Science, Kyoto University
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- Tanikaga Rikuhei
- Department of Chemistry, Faculty of Science, Kyoto University
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- Ono Noboru
- Department of Chemistry, Faculty of Science, Kyoto University
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- Kaji Aritsune
- Department of Chemistry, Faculty of Science, Kyoto University
書誌事項
- タイトル別名
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- Reaction of dimethyl sulfoxide-trifluoroacetic anhydride with anilines, phenols, and thiophenols.
説明
The reaction of dimethyl sulfoxide–trifluoroacetic anhydride complex with anilines, phenols, and thiophenols was studied, and the following results were obtained. (1) The yields of a methylthiomethylated product were improved with anilines. The reaction proceeded without significant amount of tar, the unreacted anilines being easily recovered. (2) Selective ortho-methylthiomethylation took place with phenols in good yields at lower temperature, para-methylthiomethylation occurring at higher temperature. (3) Methylthiomethylation took place with thiophenols on a sulfur atom of thiophenol at room temperature in a simple process.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 50 (2), 447-452, 1977
公益社団法人 日本化学会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282679113907712
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- NII論文ID
- 130001970843
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- ISSN
- 13480634
- 21992924
- 00092673
- 00092975
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- 抄録ライセンスフラグ
- 使用不可