Reactivity of Electrogenerated Superoxide Ion. I. Autoxidation of 9,10-Dihydroanthracene
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- Tezuka Meguru
- Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo
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- Ohkatsu Yasukazu
- Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo
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- Osa Tetsuo
- Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo
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説明
The superoxide ion, which was generated by means of electroreduction of the oxygen molecule dissolved in pyridine, abstracted the labile hydrogen from 9,10-dihydroanthracene and yielded anthraquinone and anthracene as the final products. From the products and their kinetics, the reaction was proposed to be a radical-chain autoxidation. Reactions with some other hydrocarbons were also carried out. The addition of ferrous or cobaltous phthalocyanine to the reaction system resulted in the increase of the reaction rate. A discussion of the effects led to the postulation of the intermediate formation of the superoxide ion-metal phthalocyanine complex.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 48 (5), 1471-1474, 1975
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679114717056
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- NII論文ID
- 130001972216
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- ISSN
- 13480634
- 00092673
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可