Preferential Crystallization of Lanthanoid Tris(β-diketonates) with Bridged Bis(2-pyridylmethyl)amine Ligands toward Separation Application
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- Yano Masafumi
- Faculty of Chemistry, Material and Bioengineering, Kansai University
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- Takemoto Hidehiro
- Faculty of Chemistry, Material and Bioengineering, Kansai University
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- Tatsumi Masakazu
- Faculty of Chemistry, Material and Bioengineering, Kansai University
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- Miyake Hiroyuki
- Department of Chemistry, Graduate School of Science, Osaka City University
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- Tsukube Hiroshi
- Department of Chemistry, Graduate School of Science, Osaka City University JST-CREST, Osaka City University
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説明
A combination of two bridged bis(2-pyridylmethyl)amine-type ligands offered efficient separation of lanthanoid tris(β-diketonates) complexes. The employed ligands bridged two lanthanoid tris(β-diketonates) to form crystalline ternary complexes. Since the complexes containing larger lanthanoid centers were preferentially precipitated, the bridging ligands selectively recognized the lanthanoid tris(β-diketonates) in the crystallization process, and offered an efficient separation method.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 85 (4), 490-496, 2012
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679118862592
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- NII論文ID
- 130004153052
- 10030543912
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- NII書誌ID
- AA00580132
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- COI
- 1:CAS:528:DC%2BC38Xms1ejtr0%3D
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- ISSN
- 13480634
- 00092673
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- NDL書誌ID
- 023577834
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- KAKEN
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- 使用不可