Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by (S)-1-Alkyl-2-(arylamino)methylpyrrolidine

DOI DOI PDF Web Site 被引用文献2件 参考文献98件
  • Hosoda Naoya
    Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University
  • Ito Hiroki
    Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University
  • Takimoto Tatsuya
    Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University
  • Asami Masatoshi
    Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University

書誌事項

タイトル別名
  • Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by (<i>S</i>)-1-Alkyl-2-(arylamino)methylpyrrolidine
  • ChemInform Abstract: Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by (S)‐1‐Alkyl‐2‐(arylamino)methylpyrrolidine.
公開日
2012
資源種別
journal article
DOI
  • 10.1246/bcsj.20120105
  • 10.1002/chin.201303026
公開者
公益社団法人 日本化学会

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説明

Several chiral diamines, (S)-1-alkyl-2-(arylamino)methylpyrrolidine, were used as chiral catalysts for the enantioselective addition of diethylzinc to aldehydes. The best results were obtained by employing 0.15 equiv of (S)-2-anilinomethyl-1-benzylpyrrolidine, and chiral secondary alcohols were obtained with high enantiomeric excesses (up to 94% ee).

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