Inter-basepair Hydrogen Bonds in DNA.

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Inter-basepair H-bonds in DNA are examined in the light of some crystal structures. An inter-basepair bond can be made on the major groove side from a Ci; base to the Wi+1 base. Such a bond can bridge two bases in CC/GG, CA/TG, AC/GT, and AA/TT steps. Inter-basepair H-bonds can stabilise different conformations of the basepair steps depending on the DNA sequences, and thereby can determine particular superstructures of DNA.

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