A NEW POLYENE ANTIBIOTIC, FLAVOMYCOIN STRUCTURAL INVESTIGATIONS. II

DOI PubMed
  • SCHLEGEL ROLF
    Deutsche Akademie der Wissenschaften zu Berlin, Zentralinstitut für Mikrobiologie und Experimentelle Therapie
  • THRUM HEINZ
    Deutsche Akademie der Wissenschaften zu Berlin, Zentralinstitut für Mikrobiologie und Experimentelle Therapie

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Description

The polyene antibiotic flavomycoin contains a pentaene chromophore which is conjugated with the lactone carbonyl group. This fact was proved by reduction of flavomycoin with lithium aluminum hydride, by low temperature ultraviolet spectroscopy and the infrared absorption of perhydro-flavomycoin. Oxidative degradation of perhydro-flavomycoin resulted in 2-methyl-tridecane-1, 13-dioic acid which was identified by gas chromatography and mass spectrometry. A partial formula for flavomycoin is given.

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Details 詳細情報について

  • CRID
    1390282679131804288
  • NII Article ID
    130003498395
  • DOI
    10.7164/antibiotics.24.368
  • COI
    1:CAS:528:DyaE38Xht1Ggsb8%3D
  • ISSN
    18811469
    00218820
  • PubMed
    5091213
  • Text Lang
    en
  • Article Type
    journal article
  • Data Source
    • JaLC
    • Crossref
    • PubMed
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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