Mössbauer Spectra of Isolated Molecules and Thin Films

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Other Title
  • 孤立分子・薄膜のメスバウアースペクトル(応用)
  • メスバウアースペクトロメトリーの基礎と応用 孤立分子・薄膜のメスバウアースペクトル(応用)
  • メスバウアースペクトロメトリー ノ キソ ト オウヨウ コリツ ブンシ ・ ハクマク ノ メスバウアースペクトル(オウヨウ)
  • M^|^ouml;ssbauer Spectra of Isolated Molecules and Thin Films

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Abstract

Matrix isolation is a very useful technique to measure Mössbauer spectra of isolated atoms, molecules, and unstable species, and it provides information on their electronic structures. Photochemistry of organometallic compounds, such as Fe(acac)3 and Fe(CO)5, were studied. Matrix isolation technique was applied for measurements of unstable species produced by reactions of laser-evaporated iron atoms and various reactant gases.<br>Shape of material may affect the chemical structures, and particles and thin films may have unique properties which are not obtainable in normal bulk solid materials. Mössbauer spectrometry provides direct information on composition and magnetic orientation of the iron based materials. Studies on iron films and iron based material films produced pulsed-laser deposition are demonstrated.

Journal

  • RADIOISOTOPES

    RADIOISOTOPES 62 (4), 235-250, 2013

    Japan Radioisotope Association

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