Impregnation Process of Insoluble Cobalt Ferrocyanide onto Anion-Exchange Fiber Prepared by Radiation-Induced Graft Polymerization
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- SUGIYAMA Mai
- Department of Applied Chemistry and Biotechnology, Chiba University
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- GOTO Shota
- Department of Applied Chemistry and Biotechnology, Chiba University
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- KOJIMA Takashi
- Department of Applied Chemistry and Biotechnology, Chiba University
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- FUJIWARA Kunio
- KJK Co., Ltd.
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- SUGO Takanobu
- KJK Co., Ltd.
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- UMENO Daisuke
- Department of Applied Chemistry and Biotechnology, Chiba University
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- SAITO Kyoichi
- Department of Applied Chemistry and Biotechnology, Chiba University
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説明
The impregnation process of insoluble cobalt hexacyanidoferrate(II) onto an anion-exchange fiber was clarified. Vinylbenzyl trimethylammonium chloride and N-vinyl pyrrolidone were cograft-polymerized onto a 6-nylon fiber with an average diameter of 40μm to obtain an anion-exchange capacity of 0.61 mmol/g. Hexacyanidoferrate(II) ions were adsorbed onto the anion-exchange fiber uniformly across the fiber. Subsequently, by immersing the fiber into cobalt chloride solution, hexacyanidoferrate(II) ions were quantitatively reacted with cobalt ions to form a precipitate at the periphery of the fiber. No leakage of this precipitate to the external solution was detected. The impregnation percentage, defined as the mass content of the precipitate in the resultant fiber, was 6.6%.
収録刊行物
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- RADIOISOTOPES
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RADIOISOTOPES 64 (4), 219-228, 2015
公益社団法人 日本アイソトープ協会
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詳細情報 詳細情報について
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- CRID
- 1390282679132551424
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- NII論文ID
- 130005067237
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- NII書誌ID
- AN00351589
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- ISSN
- 18844111
- 00338303
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- NDL書誌ID
- 026355955
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可