中性子照射したトリスアセチルアセトナトコバルトおよびクロムのベンゼン溶液中における反跳化学種の挙動

書誌事項

タイトル別名
  • Chemical behavior of recoil species in benzene solutions of neutron-irradiated tris(acetylacetonato)cobalt(III) and tris(acetylacetonato)chromium(III).

この論文をさがす

説明

Neutron-irradiatedCo (acac) 3or Cr (acac) 3 was dissolved in benzene containing various metal acetylacetonates as additives and the change in the apparent60Co-or51Cr-retention with the time after the dissolution was investigated at various temperatures. Unstable metal acetylacetonates such asMg (acac) 2 were found to enhance thermal reactions (or the apparent retention) in the solutions. The behavior of the recoil species was very similar in both the irradiated benzene solutions and benzene solutions of the irradiated solids of these complexes. The reactions of the recoil species in solutions of the irradiatedCo (acac) 3orCr (acac) 3and the effects of various additives in such systems (especially the correlation between the apparent scavenging power of metal salts and the stability constant of their acetylacetonates) were explained in terms of recombination, scavenging and ligand transfer reactions.

収録刊行物

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ