The studies on the solanaceous plants. Part 22. Structures of two new steroidal glycosides, soladulcosides A and B from Solanum dulcamara.

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The structures of two new steroidal glycosides named soladulcosides A and B, isolated from the aerial parts of Solanum dulcamara including new sapogenols, were elucidated as (22R, 25R)-3β, 15β, 23α-trihydroxy-5α-spirostan-26-one 3-O-α-L-rhamnopyranosyl-(1→2)-β-D-glucopyranoside and (22R, 25R)-3β, 23α-dihydroxy-5α-spirostan-26-one 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-rhamnopyranosyl-(1→4)]-β-D-glycopyranoside, respectively.

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