Synthesis of Octahydrobenzo(b)furans Using Tandem Conjugate Addition Reactions Initiated by Oxygen Nucleophile.
書誌事項
- タイトル別名
-
- Synthesis of Octahydrobenzo b furans Us
この論文をさがす
抄録
When 1-nitrocyclohexene (1) was treated with methyl 4-hydroxy-2-butynoate (2) in the presence of potassium tert-butoxide in tetrahydrofuran-tert-butanol at 0°C for 10 min, a tandem conjugate addition product, methyl cis-3a-nitrooctahydrobenzo[b]furan-Δ3, α-acetate (3a), was obtained in quantitative yield as a 55 : 45 mixture of the (Z)- and (E)-isomers. The scope and limitations of this reaction were examined. Some transformation reactions of 3a are also described.
収録刊行物
-
- ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ
-
ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ 46 (5), 744-748, 1998
公益社団法人 日本薬学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282679136577152
-
- NII論文ID
- 130003947596
- 110003662858
-
- NII書誌ID
- AA00602100
-
- COI
- 1:CAS:528:DyaK1cXjt1Gntb8%3D
-
- ISSN
- 13475223
- 00092363
-
- NDL書誌ID
- 4486180
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可