Influence of the Conformation of Methoxy-(2-naphthyl)acetates (2NMA Esters) on Their Chemical Reactions.

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Abstract

An SN2 reaction (NaI) of 1, 7-di(methanesulfoxyl)heptadien-4-yl methoxy-(2-naphthyl)acetate and a tributyltin hydride reduction of 1, 7-diiodo-4-yl methoxy-(2-naphthyl)acetate (2NMA) is crucial for determination of the absolute configuration of secondary alcohols.

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