Novel Catalytic Asymmetric Sulfoxidation in Water Using the Hypervalent Iodine Reagent Iodoxybenzene.

TOHMA Hirofumi, TAKIZAWA Shinobu, MORIOKA Hironori, MAEGAWA Tomohiro, KITA Yasuyuki

doi:10.1002/chin.200033091

Bibliographic Information

Other Title

ChemInform Abstract: Novel Catalytic Asymmetric Sulfoxidation in Water Using the Hypervalent Iodine Reagent Iodoxybenzene.

Description

A ne catalytic asymmetric oxidation of sulfides to sulfoxides in water using the hypervalent iodine(V) reagent iodoxybenzene (PhIO₂) has been developed. This methodology is distinctly different from the previously reported use of cyclodextrins or biological catalysts and provides a new route to asymmetric sulfoxidation in water.

Journal

Chemical and Pharmaceutical Bulletin

Chemical and Pharmaceutical Bulletin 48 (3), 445-446, 2000

The Pharmaceutical Society of Japan

Keywords

Details 詳細情報について

CRID: 1390282679136808704

NII Article ID: 130003948077

DOI: 10.1248/cpb.48.445; 10.1002/chin.200033091

COI: 1:CAS:528:DC%2BD3cXhslahsbc%3D

ISSN: 13475223; 15222667; 00092363; 09317597

PubMed: 10726876

Web Site: http://www.jstage.jst.go.jp/article/cpb1958/48/3/48_3_445/_pdf

Text Lang: en

Article Type: journal article

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