Depurination of Adenosine and Deoxyadenosine Monophosphates in the Hemin-hydroperoxide System.

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  • Depurination of Adenosine and Deoxyaden

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The adenine base was liberated by the oxidative cleavage of the N-glycosidic bond of substrates (5'- and 3'-AMP, 5'- and 3'-dAMP) in the hemin-cumene hydroperoxide system, which was accelerated in the presence of 1-methylimidazole.

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