13C Assignment of Diastereotopic C-26 and -27 Methyl Groups of 24-Methylenecholesterol: Steric Course of Hydrogen Migration from C-24 to C-25 during Its Biosynthesis in Higher Plants.

DOI DOI Web Site Web Site 被引用文献1件 参考文献12件 オープンアクセス

書誌事項

タイトル別名
  • 13C Assignment of Diastereotopic C-26 a

この論文をさがす

説明

Chemical shifts of the diastereotopic methyl groups (C-26 and C-27) of 24-methylenecholesterol have been unambiguously assigned by synthesizing stereochemically defined 13C-labeled compounds. This allowed us to establish the steric course of hydrogen migration from C-24 to C-25 during the formation of 24-methylenecholesterol from a Δ24-precursor in a tissue culture of Catharanthus roseus.

収録刊行物

被引用文献 (1)*注記

もっと見る

参考文献 (12)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ