New Entry of Coupling Reaction of Phenacylamine Derivatives with Silylstannane.

DOI Web Site Web Site PubMed 参考文献27件
  • Iwai Yasumasa
    Graduate School of Pharmaceutical Sciences, The University of Tokushima
  • Kita Kumiko
    Graduate School of Pharmaceutical Sciences, The University of Tokushima
  • Matsushita Yoko
    Graduate School of Pharmaceutical Sciences, The University of Tokushima
  • Yamauchi Aiko
    Graduate School of Pharmaceutical Sciences, The University of Tokushima
  • Kihara Masaru
    Graduate School of Pharmaceutical Sciences, The University of Tokushima

この論文をさがす

抄録

The new coupling reaction of phenacylamines with silylstannane and lithium diisopropylamide (LDA) is reported. The treatment of a phenacylamine iodide 1 with (trimethylsilyl)tributylstannane (Me3SiSnBu3) and cesium fluoride (CsF) gave a dimerization product 2 having no iodine atom. Reaction of 1 with LDA afforded a dimerization product 3 with an iodine atom. The products 2 and 3 were separated to the meso and racemic isomers, respectively.

収録刊行物

参考文献 (27)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ