Monoterpenoid Glycosides of Glehnia littoralis Root and Rhizoma.

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  • Monoterpenoid Glycosides of Glehnia lit

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From the methanolic extract of the root and rhizoma of Glehnia littoralis FR. SCHMIDT ex MIQ. (Umbelliferae, Hamabofu in Japanese), five new monoterpenoid glycosides were isolated together with (+)- and (-)-angelicoidenol 2-O-β-D-glucopyranoside. Based on the results of spectral investigation, they were characterized as (-)-angelicoidenol 2-O-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside, (2R, 6S)-bornane-2, 6-diol 2-O-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside, (2R)-bornane-2, 9-diol 2-O-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside, and (4R)- and (4S)-p-menth-1-ene-7, 8-diol 8-O-β-D-apiofuranosyl-(1→6)-β-D-glucopyranosides, respectively.

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