A Facile Method for the Stereoselective Horner-Wadsworth-Emmons Reaction of Aryl Alkyl Ketones.
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- Sano Shigeki
- Faculty of Pharmaceutical Sciences, The University of Tokushima
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- Yokoyama Kenji
- Faculty of Pharmaceutical Sciences, The University of Tokushima
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- Shiro Motoo
- Rigaku Corporation
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- Nagao Yoshimitsu
- Faculty of Pharmaceutical Sciences, The University of Tokushima
Bibliographic Information
- Other Title
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- Facile Method for the Stereoselective Horner Wadsworth Emmons Reaction of Aryl Alkyl Ketones
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Abstract
Excellent Z or E selectivity was observed in the Horner–Wadsworth–Emmons (HWE) reactions of methyl bis(2,2,2-trifluoroethyl)phosphonoacetate or ethyl 2-fluoro-2-diethylphosphonoacetate with aryl alkyl ketones bearing substituents on an aromatic moiety employing Sn(OSO2CF3)2 in the presence of N-ethylpiperidine.
Journal
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- Chemical and Pharmaceutical Bulletin
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Chemical and Pharmaceutical Bulletin 50 (5), 706-709, 2002
The Pharmaceutical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679140850688
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- NII Article ID
- 110003616234
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- NII Book ID
- AA00602100
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- COI
- 1:CAS:528:DC%2BD38Xks12ks7w%3D
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- ISSN
- 13475223
- 00092363
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- NDL BIB ID
- 6155942
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- PubMed
- 12036038
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- Abstract License Flag
- Disallowed
