Thio-Sugars. (4) Synthesis of Carbohydrate l,3-Glycol (Six-Membered) Thionocarbonates and Their Attempted O-S Rearrangement
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- TSUDA Yoshisuke
- Faculty of Pharmaceutical Sciences, Kanazawa University
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- NOGUCHI Shinsuke
- Faculty of Pharmaceutical Sciences, Kanazawa University
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- NIINO Hideki
- R&D Research Center, Permachem Asia Ltd.
書誌事項
- タイトル別名
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- Utilization of Sugars in Organic Synthesis. Part XXXIV. Thio-Sugars. IV. Synthesis of Carbohydrate 1,3-Glycol (Six-Membered) Thionocarbonates and Their Attempted O-S Rearrangement.
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抄録
Four six-membered cyclic thionocarbonates (two sec-sec and two prim-sec) were prepared and their radical-promoted O-S rearrangement reaction was examined. The results revealed that the reaction in six-membered rings is difficult compared with the simple rearrangement in five-membered rings. In the course of syntheses of the substrates, interesting acyl migration during the stannylation process occurred.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 49 (9), 1210-1213, 2001
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390282679141129216
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- NII論文ID
- 110003616079
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- NII書誌ID
- AA00602100
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- COI
- 1:CAS:528:DC%2BD3MXmsFykt7c%3D
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- ISSN
- 13475223
- 00092363
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- NDL書誌ID
- 5893058
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- PubMed
- 11558616
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可