Studies on organic fluorine compounds. IL The ene reaction of trifluoroacetone.

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書誌事項

公開日
1986
DOI
  • 10.1248/cpb.34.1546
公開者
公益社団法人 日本薬学会

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説明

The ene reaction of 1, 1, 1-trifluoroacetone with various olefinic compounds proceeded in the presence of aluminum chloride at low temperature to give allylmethyl (trifluoromethyl)carbinols. Olefinic compounds with a terminal vinyl group reacted smoothyl, but some olefins with an inner double bond did not react at all. Trifluoroacetone was also found to undergo a Friedel-Crafts type reaction with aromatic compounds.

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