Studies on the constituents of Aceraceae Plants. II. Structure of aceroside I, a glucose of a novel cyclic diarylheptanoids from Acer nikoense Maxim
書誌事項
- タイトル別名
-
- Studies on the constituents of aceraceae plants. II. Structure of aceroside I, a glucoside of a novel cyclic diarylheptanoid from Acer nikoense Maxim.
この論文をさがす
説明
The structure of aceroside I, C25H32O8, mp 170-171°(acetone), [α]20D-7.7°, which was isolated from the stem bark of Acer nikoense MAXIM. (Aceraceae), was established to be acerogenin A β-D-glucopyranoside represented by formula 1. Acerogenin A, C19H22O3, mp 151-152°, [α]20D+57.3°, was concluded to be a m-, p'-bridged diphenyl ether type diarylheptanoid (2) on the basis of chemical and spectroscopic (especially NMR) evidences. The stereostructure of 2 was determined by derivation of acerogenin A (2) into (S)-1-(p-hydroxyphenyl)-7-(p-methoxyphenyl)-heptan-3-ol. Acerogenin A (2) is the first example of a novel type of diarylheptanoid-20-oxa-[7, 1]-metapara-cyclophane.
収録刊行物
-
- ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ
-
ＣＨＥＭＩＣＡＬ ＆ ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ ＢＵＬＬＥＴＩＮ 26 (9), 2805-2810, 1978
公益社団法人 日本薬学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282679144826112
-
- NII論文ID
- 110003623375
-
- NII書誌ID
- AA00602100
-
- COI
- 1:CAS:528:DyaE1MXitlGqtQ%3D%3D
-
- ISSN
- 13475223
- 00092363
- http://id.crossref.org/issn/00092363
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可
