Zn-Proline Catalyzed Selective Synthesis of 1,2-Disubstituted Benzimidazoles in Water

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Zn-proline (5 mol%) performs as a novel water-soluble and recyclable Lewis acid catalyst for the selective synthesis of 1,2-disubstituted benzimidazoles from wide range of substituted o-phenylenediamines and aldehydes in moderate to excellent isolated yields (42—92%) using water as solvent at ambient temperature.

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