Novel system for decarboxylative bromination of α,β-unsaturated carboxylic acids with diacetoxyiodobenzene

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  • Fursule Ravindra Abhykumar
    Department of Pharmaceutical Chemistry, H. R. Patel Institute of Pharmaceutical Education and Research
  • Patil Pravin Onkar
    Department of Pharmaceutical Chemistry, H. R. Patel Institute of Pharmaceutical Education and Research
  • Shewale Bharti Devaji
    Department of Pharmaceutical Chemistry, H. R. Patel Institute of Pharmaceutical Education and Research
  • Kosalge Satish Bhaskar
    Department of Pharmaceutical Chemistry, H. R. Patel Institute of Pharmaceutical Education and Research
  • Deshmukh Prashant Krishnarao
    Department of Pharmaceutical Chemistry, H. R. Patel Institute of Pharmaceutical Education and Research
  • Patil Dilip Ashok
    Department of Pharmaceutical Chemistry, H. R. Patel Institute of Pharmaceutical Education and Research

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タイトル別名
  • Novel System for Decarboxylative Bromination of .ALPHA.,.BETA.-Unsaturated Carboxylic Acids with Diacetoxyiodobenzene
  • Novel system for decarboxylative bromination of a v unsaturated carboxylic acids with diacetoxyiodobenzene

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A simple and mild method for the conversion of varieties of α,β-unsaturated carboxylic acids to the corresponding bromoalkenes using diacetoxyiodobenzene (IBD) in combination with tetraethyl-ammonium bromide (TEAB) at room temperature is discussed. Advantages of this system are short reaction time, easy work up and gave good to excellent yields.

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