X-Ray Structure Characterization of Palladium(II) Ternary Complexes of Pyridinedicarboxylic and Phthalic Acid with Phenanthroline and Bipyridine
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- Wang Yue
- Lab of Inorganic Chemistry, China Pharmaceutical University
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- Okabe Nobuo
- Faculty of Pharmaceutical Sciences, Kinki University
Bibliographic Information
- Other Title
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- X Ray Structure Characterization of Palladium 2 Ternary Complexes of Pyridinedicarboxylic and Phthalic Acid with Phenanthroline and Bipyridine
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Abstract
The crystal structures of the series of four ternary complexes, [Pd(phen)(2,6-PDCA)]·4H2O (1) (phen=1,10-phenanthroline; 2,6-PDCA=2,6-pyridinedicarboxylic acid), [Pd(bpy)(2,3-PDCA)]·3H2O (2) (bpy=2,2′-bipyridineand; 2,3-PDCA=2,3-pyridinedicarboxylic acid) and [Pd(phen)(PHT)]·2.5H2O (3) (PHT=o-phthalic acid ) and [Pd(bpy)(PHT)]·1.5H2O (4), are determined and the coordination modes of palladium(II) ternary complexes are characterized. All complexes take the mononuclear Pd(II) complexes, in which central Pd(II) atom of each complex has a similar distorted square-planar four coordination geometry. In all complexes, the aromatic heterocyclic compounds, phen and bpy, behave as a bidentate N, N′ ligand. In the complex 1 and 2, 2,6-PDCA and 2,3-PDCA behave as a bidentate N, O ligand, and in complex 3 and 4, PHT behaves as a bidentate O, O′ ligand.
Journal
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- Chemical and Pharmaceutical Bulletin
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Chemical and Pharmaceutical Bulletin 53 (4), 366-373, 2005
The Pharmaceutical Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679146429440
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- NII Article ID
- 10016652888
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- NII Book ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- NDL BIB ID
- 7292031
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- PubMed
- 15802833
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- Abstract License Flag
- Disallowed